Product Name :
2-Azaadamantane-N-oxyl (CAS 57625-08-8)
Synonym :
AZADO
Application :
CAS:
57625-08-8
Purity:
96%
Molecular Weight:
152.21
Formula :
C9H14NO
Physical state:
Solid
solubility :
Shipping Condition :
Store at 4° C
Melting point:
182-189° C (dec.)
SMILES:
C1C2CC3CC1CC(C2)N3[O]
References:
:2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO: highly efficient organocatalysts for oxidation of alcohols. | Shibuya, M., et al. 2006. J Am Chem Soc. 128: 8412-3. PMID: 16802802A chemoenzymatic approach to enantiomerically pure amines using dynamic kinetic resolution: application to the synthesis of norsertraline. | Thalén, LK., et al. 2009. Chemistry. 15: 3403-10. PMID: 19222068TEMPO electromediated oxidation of some polysaccharides including regenerated cellulose fiber. | Isogai, T., et al. 2010. Biomacromolecules. 11: 1593-9. PMID: 20469944Speedy and clean hypervalent iodine/nitroxyl radical mediated oxidation of alcohols using recyclable adamantane reagent with highly active 2-azaadamantane-N-oxyl organocatalyst. | Dohi, T., et al. 2012. Chem Pharm Bull (Tokyo). 60: 1442-7. PMID: 23124568Discovery and exploitation of AZADO: the highly active catalyst for alcohol oxidation.N-Desethyl amodiaquine dihydrochloride Formula | Iwabuchi, Y.5-(Difluoromethoxy)pyridin-2-amine uses 2013.PMID:33602106 Chem Pharm Bull (Tokyo). 61: 1197-213. PMID: 24292782Highly chemoselective aerobic oxidation of amino alcohols into amino carbonyl compounds. | Sasano, Y., et al. 2014. Angew Chem Int Ed Engl. 53: 3236-40. PMID: 24554411Highly efficient aerobic oxidation of alcohols by using less-hindered nitroxyl-radical/copper catalysis: optimum catalyst combinations and their substrate scope. | Sasano, Y., et al. 2015. Chem Asian J. 10: 1004-9. PMID: 25620279Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects. | Rafiee, M., et al. 2015. J Am Chem Soc. 137: 14751-7. PMID: 26505317Total Synthesis and Biological Evaluation of Irciniastatin A (a.k.a. Psymberin) and Irciniastatin B. | Uesugi, S., et al. 2015. J Org Chem. 80: 12333-50. PMID: 26544018Understanding the fundamentals of redox mediators in Li-O2 batteries: a case study on nitroxides. | Bergner, BJ., et al. 2015. Phys Chem Chem Phys. 17: 31769-79. PMID: 26563563Chemoselective Conversion from alpha -Hydroxy Acids to alpha -Keto Acids Enabled by Nitroxyl-Radical-Catalyzed Aerobic Oxidation. | Furukawa, K., et al. 2016. Org Lett. 18: 4230-3. PMID: 27533283C-H Activation from Iron(II)-Nitroxido Complexes. | Kleinlein, C., et al. 2017. Angew Chem Int Ed Engl. 56: 12197-12201. PMID: 287663252-Azaadamantane N-oxyl (AZADO)/Cu Catalysis Enables Chemoselective Aerobic Oxidation of Alcohols Containing Electron-Rich Divalent Sulfur Functionalities. | Sasano, Y., et al. 2018. Org Lett. 20: 6104-6107. PMID: 30226058Radical Dimerization in a Plastic Organic Crystal Leads to Structural and Magnetic Bistability with Wide Thermal Hysteresis. | Dragulescu-Andrasi, A., et al. 2019. J Am Chem Soc. 141: 17989-17994. PMID: 31661269Electrochemical reactions of highly active nitroxyl radicals with thiol compounds. | Kumano, M., et al. 2023. Anal Sci. 39: 369-374. PMID: 36576651